#Sulfide charge free#

Xiaomei He, Hong Sun, Xiangdong Ding, Kejie Zhao.

Relaxation of the Interface Resistance between Solid Electrolyte and 5 V-Class Positive Electrode.

Ryo Nakayama, Kazunori Nishio, Daisuke Imazeki, Naoto Nakamura, Ryota Shimizu, Taro Hitosugi.

Investigation of Delamination-Induced Performance Decay at the Cathode/LLZO Interface.

Pallab Barai, Tomas Rojas, Badri Narayanan, Anh T.

ACS Applied Materials & Interfaces 2021, 13 Reactivity and Potential Profile across the Electrochemical LiCoO2–Li3PS4 Interface Probed by Operando X-ray Photoelectron Spectroscopy. The Journal of Physical Chemistry C 2021, 125 Thermodynamic Analysis of Li-Intercalated Graphite by First-Principles Calculations with Vibrational and Configurational Contributions.

Jun Haruyama, Shigeharu Takagi, Keiji Shimoda, Iwao Watanabe, Keitaro Sodeyama, Tamio Ikeshoji, Minoru Otani.

ACS Applied Materials & Interfaces 2022, 14 New Insights into the Effects of Zr Substitution and Carbon Additive on Li3–圎r1–xZrxCl6 Halide Solid Electrolytes.

Qinong Shao, Chenhui Yan, Mingxi Gao, Wubin Du, Jian Chen, Yaxiong Yang, Jiantuo Gan, Zhijun Wu, Wenping Sun, Yinzhu Jiang, Yongfeng Liu, Mingxia Gao, Hongge Pan.

Probing the Lithium Substructure and Ionic Conductivity of the Solid Electrolyte Li4PS4I.

Florian Strauss, Jing Lin, Leonhard Karger, Daniel Weber, Torsten Brezesinski.

Distinguishing the Effects of the Space-Charge Layer and Interfacial Side Reactions on Li10GeP2S12-Based All-Solid-State Batteries with Stoichiometric-Controlled LiCoO2.

Guozhong Lu, Fushan Geng, Suyu Gu, Chao Li, Ming Shen, Bingwen Hu.

Albina Jetybayeva Berik Uzakbaiuly Aliya Mukanova Arailym Nurpeissova Zhumabay Bakenov.Conformal Buffer Layer Coating on Ni-Rich Cathode Powder via Particle Atomic Layer Deposition for All-Solid-State Batteries. Hwichul Yang, Miju Ku, Jongheon Kim, Daye Lee, Hansam Lee, Young-Beom Kim.Immense Reduction in Interfacial Resistance between Sulfide Electrolyte and Positive Electrode. Kazunori Nishio, Daisuke Imazeki, Kosuke Kurushima, Yuki Takeda, Kurei Edamura, Ryo Nakayama, Ryota Shimizu, Taro Hitosugi.Which Exchange Current Densities Can Be Achieved in Composite Cathodes of Bulk-Type All-Solid-State Batteries? A Comparative Case Study. Vanessa Miß, Asvitha Ramanayagam, Bernhard Roling.This article is cited by 310 publications. These aspects on the atomic scale will give a useful perspective for the further improvement of the ASS-LIB performance.

#Sulfide charge free#

The LNO interposition suppresses this growth of SCL and provides smooth Li transport paths free from the possible bottlenecks. The calculated energies of the Li-vacancy formation and the Li migration reveal that subsurface Li in the LPS side can begin to transfer at the under-voltage condition in the LCO/LPS interface, which suggests the SCL growth at the beginning of charging, leading to the interfacial resistance. The LCO/LPS interface has attractive Li adsorption sites and rather disordered structure, whereas the interposition of the LNO buffer layers forms smooth interfaces without Li adsorption sites for both LCO and LPS sides. The DFT+U calculations, coupling with a systematic procedure for interface matching, showed the stable structures and the electronic states of the interfaces. As a most representative system, we examined the interfaces between LiCoO 2 cathode and β-Li 3PS 4 solid electrolyte (LCO/LPS), and the LiCoO 2/LiNbO 3/β-Li 3PS 4 (LCO/LNO/LPS) interfaces with the LiNbO 3 buffer layers. We theoretically elucidated the characteristics of the space–charge layer (SCL) at interfaces between oxide cathode and sulfide electrolyte in all-solid-state lithium-ion batteries (ASS-LIBs) and the effect of the buffer layer interposition, for the first time, via the calculations with density functional theory (DFT) + U framework.